Magnesium Ascorbyl Phosphate Powder

Magnesium Ascorbyl Phosphate Powder

1. Specification: 98.0% – 102.0% (on dried basis)
2. Sample: Sample Available
3. Test method: HPLC / Titration / ICP-MS
4. Synonyms: MAP, Magnesium ascorbyl phosphate, Vitamin C phosphate magnesium salt, Ascorbic acid phosphate magnesium salt
5. Appearance: Fine, free‑flowing white to pale yellowish-white powder; odorless
6. Particle size: >95% pass 80 mesh
7. MOQ: 1 KG
8. Package: 1kg/foil bag (double-sealed, light‑protected), 25kgs/fiber drum
9. Certificate: HACCP, ISO 22000, HALAL, GMP, Kosher (available upon request)
10. Molecular Formula: C₆H₇O₉P·Mg (typically C₆H₇MgO₉P · nH₂O)
11. CAS number: 114040-31-2 (anhydrous); 113170-55-1 (hydrated)
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Description

 

Magnesium Ascorbyl Phosphate Powder

Vitamin C (L‑ascorbic acid) is a skincare legend - brightening, antioxidant, collagen‑boosting. But it has a fatal flaw: it's neurotic. It oxidizes if you look at it wrong. It hates light. It hates air. It hates pH above 3.5. It hates metal ions. And it stings like a bee when you put it on sensitive skin.

Magnesium Ascorbyl Phosphate (MAP) is the version that went to therapy and learned to chill.

MAP is a phosphate ester of ascorbic acid. We've attached a phosphate group to the 3‑position hydroxyl, and neutralized the molecule with a magnesium ion. This simple chemical modification turns the diva vitamin C into a stable, non‑irritating, easy‑to‑formulate active that actually survives in a bottle.

The "Phosphate Shield": The phosphate group acts like a suit of armor. It protects the ascorbic acid from oxidizing in the presence of air, light, and metal ions. MAP is stable at neutral pH (6.0–7.0) - right where your skin likes it. No more low‑pH serums that tingle (burn) upon application.

The "Enzymatic Key": MAP itself is not biologically active as vitamin C. It's a prodrug. When applied to skin, the enzyme phosphatase (abundant in the epidermis) clips off the phosphate group, releasing pure ascorbic acid directly where it's needed - slowly, over hours, providing sustained release.

MAP vs. L‑Ascorbic Acid (The Diva)

Property L‑Ascorbic Acid Magnesium Ascorbyl Phosphate
Stability (solution) Days to weeks Months (12–24 months)
pH required for stability <3.5 5.0 – 7.0
Skin irritation High (stinging) Low (non‑irritating)
Formulation difficulty Nightmare Easy
Cost Low Moderate

Specification: 98.0% – 102.0% (on dried basis)
Sample: Sample Available
Test method: HPLC / Titration / ICP-MS
Synonyms: MAP, Magnesium ascorbyl phosphate, Vitamin C phosphate magnesium salt, Ascorbic acid phosphate magnesium salt
MOQ: 1 KG  |  Package: 1kg/foil bag (double-sealed, light‑protected), 25kgs/fiber drum
Certificate: HACCP, ISO 22000, HALAL, GMP, Kosher (available upon request)
Molecular Formula: C₆H₇O₉P·Mg  |  CAS: 114040-31-2

Magnesium Ascorbyl Phosphate Powder
Product Characteristics
 
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Appearance

Fine, free‑flowing white to pale yellowish-white powder; odorless.
⚗️

Purity

≥98% - high-quality stabilized vitamin C derivative.
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Solubility

High - ≥30 g/100 mL water at 20°C. Dissolves rapidly.
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pH (5% solution)

6.0 – 8.0 - near neutral, skin‑friendly, no stinging.
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Particle Size

>95% pass 80 mesh; micronized available.
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GMP Manufacturing

Phosphorylation of ascorbic acid; purified by recrystallization.

COA (Certificate of Analysis)

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Benefits of Magnesium Ascorbyl Phosphate Powder

01Skin Brightening (Tyrosinase Inhibition)

MAP inhibits tyrosinase, reducing new melanin formation. Lightens dark spots, melasma, and post‑inflammatory hyperpigmentation (PIH). As effective as hydroquinone without the toxicity.

02Collagen Synthesis (Anti‑Aging)

Once dephosphorylated, ascorbic acid is an essential cofactor for collagen‑stabilizing enzymes. Result: firmer skin, reduced fine lines and wrinkles.

03Stable & Non‑Irritating

The phosphate shield protects against oxidation. Stable at neutral pH (6–7), no stinging, no redness. Safe for sensitive skin, rosacea, and post‑procedure skin.

04Sustained Release via Skin Phosphatase

MAP is a prodrug. Skin enzymes slowly cleave the phosphate group, releasing active vitamin C over hours - not a one‑time burst that oxidizes within minutes.

05Magnesium Bonus

The magnesium counterion supports skin barrier repair, reduces inflammation, and regulates sebum production - a teammate, not a spectator.

06Easy to Formulate

Unlike L‑ascorbic acid (pH <3.5, oxidation nightmare), MAP is stable in standard emulsions, serums, and toners. Works at neutral pH, compatible with most ingredients.

Application Fields

Skincare & Cosmetics (Hero Application): Brightening serums (3–10% MAP), anti‑aging creams (5–10% MAP), vitamin C moisturizers (2–5% MAP), eye creams (2–3% MAP), sunscreen boosters (1–2% MAP), scalp serums (2–3% MAP).
Pharmaceutical / Clinical: Post‑procedure healing gels, melasma treatment formulations (often combined with tranexamic acid and niacinamide).
OEM Finished Products: Brightening serum, anti‑aging cream, gentle vitamin C moisturizer, melasma treatment, liposomal serum, powder sticks (mix‑your‑own) - full custom manufacturing available.

Production Process

Production process of Magnesium Ascorbyl Phosphate

Product Quality Advantage

≥98% Purity – High-quality stabilized vitamin C.

Low Free Ascorbic Acid – ≤0.3% (indicates high phosphorylation).

Low Free Phosphate – ≤0.1% (formulation stability).

Neutral pH (7.0–7.5) – No low‑pH irritation.

Excellent Solubility – Dissolves instantly in cold water.

cGMP Certified – Full traceability and documentation.

GMP Facility
Quality Control Lab

Annual Capacity: 1,500 Tons | 15+ years of cosmetic active ingredient expertise

Professional ODM/OEM Services

We provide full OEM/ODM manufacturing for finished products featuring MAP as the key active ingredient.

① Finished Skincare Products
MAP 5% Brightening Serum: With hyaluronic acid and niacinamide.
MAP 10% Anti‑Aging Cream: With peptides and ceramides.
MAP 3% Gentle Vitamin C Moisturizer: For sensitive skin.
MAP + Tranexamic Acid Melasma Treatment: Power couple for dark spots.
MAP Liposomal Serum: Enhanced penetration.
MAP Vitamin C Powder Sticks: Mix‑your‑own serum - MAP powder is stable and dissolves instantly.

② Formulation Support
pH adjustment (target 6.0–7.0), preservation (MAP is not a preservative), texture optimization, stability testing (real‑time and accelerated, monitor MAP degradation via HPLC).

③ Additional Services
Third‑party certification (Kosher, HALAL), regulatory documentation (EU Cosmetic Regulation, FDA compliance).

Export Certificates

Certificates HACCP ISO HALAL GMP Kosher

Why choose us

XI'AN LANDNUTRA CO., LTD. – Your Trusted Manufacturer of Antioxidant & Functional Ingredients. Rooted in Quality, Driven by Expertise, Committed to Health and Excellence.

Strong Production Capability: Annual capacity 1,500 tons. 15+ years experience, own facility.
Leading Service: ONE-STOP OEM/ODM from pre-sales to after-sales.
Quality Assurance: CQC-certified enterprise, purity embedded in every process.
Broad Market: Botanical Extracts, Cosmetic Ingredients, Functional Ingredients.

15+ years of cosmetic active ingredient manufacturing. cGMP‑certified facilities. Full in‑house OEM/ODM capabilities for brightening and anti‑aging products. Regulatory documentation for global markets. Batch‑specific COA including assay, free ascorbic acid, free phosphate, magnesium content, and heavy metals. Technical support for formulation (stability, pH adjustment, compatibility).

FAQ

Q1: Is MAP better than L‑ascorbic acid (pure vitamin C)?
A: They serve different purposes. L‑ascorbic acid is more potent if it stays stable and if your skin tolerates low pH. MAP is stable, non‑irritating, and easier to formulate. For most consumers (especially those with sensitive skin), MAP is the better real‑world choice. For formulators, MAP is a dream; L‑ascorbic acid is a nightmare.
Q2: Does MAP convert to vitamin C on the skin?
A: Yes. Skin contains phosphatases that cleave the phosphate group, releasing active L‑ascorbic acid. This conversion happens slowly over several hours, providing sustained activity.
Q3: Is MAP effective for dark spots?
A: Yes - multiple clinical studies confirm MAP reduces melanin index and lightens hyperpigmentation. Expect visible results in 8–12 weeks.
Q4: Can I use MAP with retinol?
A: Yes. MAP is stable at pH 6–7, compatible with retinol (pH 5.5–6.5). Use MAP AM, retinol PM. MAP also helps stabilize retinol by reducing oxidative degradation.
Q5: Is MAP safe during pregnancy?
A: Yes. MAP is non‑toxic, non‑irritating, with no teratogenic concerns. Many dermatologists recommend MAP for pregnant women who want vitamin C benefits without L‑ascorbic acid irritation.
Q6: Why does my MAP powder sometimes look pale yellow?
A: Slight yellow tint is normal. MAP has a natural off‑white to pale yellowish hue. Bright yellow or brown indicates oxidation - discard if dark yellow or has off‑odor.
Q7: Does MAP sting like L‑ascorbic acid?
A: No. MAP is non‑irritating and generally does not cause stinging. Safe around eyes, on compromised skin, and on rosacea‑prone skin.
Q8: What concentration of MAP should I use in my serum?
A: Maintenance/daily antioxidant: 2–5%; Brightening (dark spots): 5–10%; Anti‑aging: 5–10%; Post‑procedure calming: 2–3%; Maximum recommended: 15%.
Q9: Is MAP water‑soluble?
A: Yes, highly water‑soluble. Dissolves easily in cold water, producing a clear to slightly hazy solution.
Q10: What is the shelf life of MAP powder?
A: 24 months in original sealed container under cool, dry conditions (≤25°C, ≤60% RH). Protect from light. Refrigeration (2–8°C) extends shelf life to 36 months.
Q11: Can MAP be used in anhydrous formulas (oil‑based)?
A: No - MAP is water‑soluble and insoluble in oils. For anhydrous formulas, use oil‑soluble vitamin C derivatives (tetrahexyldecyl ascorbate, ascorbyl tetraisopalmitate).
Q12: Is MAP natural?
A: No - MAP is semi‑synthetic. The starting material is natural L‑ascorbic acid, but phosphorylation and neutralization are chemical processes. Acceptable in "clean" beauty but not in "100% natural" lines.

 

Test Item Specification (Cosmetic Grade) Test Result Conclusion
Appearance White to pale yellowish-white powder Conforms Pass
Assay (HPLC) 98.0% – 102.0% 99.6% Pass
Magnesium Content 7.5% – 9.0% 8.3% Pass
Free Ascorbic Acid ≤1.0% 0.3% Pass
Free Phosphate ≤0.5% 0.1% Pass
pH (5% solution) 6.0 – 8.0 7.2 Pass
Lead (Pb) ≤1.0 ppm <0.3 ppm Pass
Total Plate Count ≤1,000 cfu/g <100 cfu/g Pass
E. Coli / Salmonella Negative Negative Pass

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